Allylmagnesium chloride, 1M in MeTHF, Thermo Scientific Chemicals

Description

Allylmagnesium chloride has been used in a study of the nucleophilic ring-opening of 2-methyleneaziridines to imines and subsequent conversion to 5,5?-disubstituted hydantoins. It is also used as a reagent for the introduction of the allyl group.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Applications
Allylmagnesium chloride has been used in a study of the nucleophilic ring-opening of 2-methyleneaziridines to imines and subsequent conversion to 5,5′-disubstituted hydantoins. It is also used as a reagent for the introduction of the allyl group.

Solubility
It reacts violently with water.

Notes
Air & moisture sensitive. Stable under recommended storage conditions.

Specifications

Chemical Identifiers

• CAS: 2622-05-1
• Molecular Formula: C3H5ClMg
• Molecular Weight (g/mol): 100.83
• MDL Number: MFCD00000473
• InChI Key: PLYLAFITHJUEGX-UHFFFAOYSA-M
• Synonym: allylmagnesium chloride, magnesium, chloro-2-propenyl, magnesium, chloro-2-propen-1-yl, chloro prop-2-en-1-yl magnesium, allylmagnesium chloride solution, 2.0 m in thf, sjpdadpprujp@, allylmagnesiumchloride, allyl magnesium chloride, allyl-magnesium chloride, 2-propenyl magnesium chloride
• PubChem CID: 75804
• IUPAC Name: magnesium;prop-1-ene;chloride
• SMILES: Cl[Mg]CC=C

• Linear Formula: CH₂=CHCH₂MgCl
• Quantity: 100 mL
• UN Number: UN3399
• Sensitivity: Air and moisture sensitive
• Solubility Information: It reacts violently with water.
• Formula Weight: 100.83
• Concentration or Composition (by Analyte or Components): 1M in MeTHF
• Chemical Name or Material: Allylmagnesium chloride

Safety and Handling

Hazard Category	H225-H260-H302-H314-H335
Hazard Statement	GHS H Statement H225-H261-H314-H318 Highly flammable liquid and vapor. In contact with water releases flammable gas. Causes severe skin burns and eye damage. Causes serious eye damage.
Precautionary Statement	P210-P223-P231+P232-P233-P235-P240-P241-P242-P243-P260-P264b-P270-P271-P280-P303+P361+P353-P304+P340-P305+P351+P338-P310-P330-P331-P335+P334-P363-P370+P378q-P501c
DOTInformation	Transport Hazard Class: 4.3; Packing Group: II; Proper Shipping Name: ORGANOMETALLIC SUBSTANCE, LIQUID, WATER-REACTIVE, FLAMMABLE
TSCA	Yes
Recommended Storage	Ambient temperatures

SDS

RUO – Research Use Only